Nova Kbm Branik Maribor (SLO) – Robur Tiboni Urbino (and. 0-3) 1-3 (25-23, 24-26, 20-25, 18-25)
Smart Allianz Stoccarda (GER) – LP Salo (FIN) (and. 2-3) 3-0 (25-18, 25-18, 25-21) Golden Set: 15-6
Aluprof Bielsko-Biala (POL) – Uralochka-Ntmk Ekaterinburg (RUS) (and. 0-3) 3-0 (27-25, 26-24, 25-17) Golden Set: 15-8
Igtisadchi Baku (AZE) – Yamamay Busto Arsizio (and. 0-3) 2-3 (21-25, 25-20, 19-25, 25-18, 13-25)
Asterix Kieldrecht (BEL) – Galatasaray Istanbul (TUR) (and. 0-3) 3-2 (23-25, 25-14, 25-18, 18-25, 15-12) Golden Set: 12-15
Sagres Neuchatel (SUI) – A.E.K. Atene (GRE) (andata: 1-3) 2-3 (16-25, 26-24, 17-25, 25-22, 8-15)
Stiinta Bacau (ROU) – SVS Post Schwechat (AUT) (and. 0-3) 0-3 (22-25, 20-25, 9-25)
Dinamo Krasnodar (RUS) – Rote Raben Vilsbiburg (GER) (and. 3-1) 2-3 (25-15, 25-14, 21-25, 23-25, 13-15) Golden Set: 16-14

Così nei quarti di finale (andata: 31/01-02/02; ritorno: 07/02-09/02)

Smart Allianz Stoccarda (GER) – Robur Tiboni Urbino
Aluprof Bielsko-Biala (POL) – Yamamay Busto Arsizio
Galatasaray Istanbul (TUR) – A.E.K. Atene (GRE)
Dinamo Krasnodar (RUS) – SVS Post Schwechat (AUT)